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»ê¼ÒºÐ¼®±â ÀÛµ¿¿ø¸®(electrolyte)

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TZ-SHR-38932
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2012.03.05
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11 page / 59.3 KB
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1Àå Electrolytic Oxygen Analyzers

2Àå HerschCell

3Àå Micro Fuel Cell
1. Advantages (Micro Fuel Cell)
2. Disadvantages (Micro Fuel Cell)

  ¢ß±Â¸ð´×°èÃø±â    oxygen analyzer:   electrolytic oxygen analyzers  oxygen analyzer:   electrolytic oxygen analyzers    oxygen analyzers  electrolytic oxygen analyzers  principle of operation  
two types of electrolytic or galvanic sensors :
-hersch
-micro fuel cell
  oxygen analyzers  electrolytic oxygen   analyzers  principle of operation  in the presence of oxygen,   galvanic cells (or battery cells)   develop an electromagnetic field   as the result of a chemical   
reaction.
(°¥¹Ù´Ð¼¿Àº, »ê¼Ò¿ÍÀÇ  È­ÇйÝÀÀÀÇ°á°ú·Î¼­ÀüÀÚ±âÀåÀ»  ¹ß»ý½ÃŲ´Ù.)  current is measured and   calibrated to the oxygen   concentration  (¿©±â¼­¹ß»ýÇÑÀü·ù¸¦  ÃøÁ¤ÇÏ°í, »ê¼ÒÀÇÇÔ·®¿¡´ëÇØ  ±³Á¤ÇÑ´Ù.)    oxygen analyzers  electrolytic oxygen analyzers  principle of operation  
a depleting sensor has a measurement reaction
that consumes the anode  (¼Ò¸ð¼º¼¾¼­ÀÇ°æ¿ì, Àü±ØÀ»¼Ò¸ð½ÃÅ°´Â  ¹ÝÀÀÀ¸·ÎÀü·ù¸¦¹ß»ý½ÃŲ´Ù.)  the electrode lifetime is limited   (Àü±ØÀǼö¸íÀÌÁ¦ÇÑÀûÀÌ´Ù.)    oxygen analyzers  electrolytic oxygen   analyzers:  herschcell  principle of operation  sensitive, uhp versions have ldl down   to 1 ppb  (ÃøÁ¤À̹ΰ¨ÇÏ°í, ÃÊ°í¼øµµ¿ëÀºÃÖÀú  1ppb ±îÁöÃøÁ¤ÀÌ°¡´É)  sample is in direct contact with the   electrolyte & contaminants can quickly   degrade the electrolyte and possibly   poison the silver cathode  (½Ã·á´ÂÀüÇؾװúÁ÷Á¢Á¢ÃË&   ¿À¿°¹°ÁúÀºÀüÇؾ×ÀÇÇ°¼ºÀ»±Þ°ÝÈ÷  ¶³¾î¶ß¸®°ÔµÇ¾îÀü±Ø¿¡¾Ç¿µÇâÀ»  ¹ÌÄ£´Ù.)  cathodecathodeanode  protection  electrodeelectrode  samplesample  koh electrolyte  oh      oxygen analyzers  electrolytic oxygen   analyzers:  herschcell  principle of operation  bubbling sample gas causes rapid   evaporation and requires frequent   water addition, which can cause   spiking.bubbling causes noise, and   the sensor is very sensitive to   sample flow changes  (°ÅÇ°À»ÀÏÀ¸Å°´Â½Ã·á°¡½º´Â¼öºÐÀÇ  Áõ¹ßÀ»¾ß±â½ÃŲ´Ù.°ÅÇ°Àºnoise¸¦  ¹ß»ý½ÃÅ°±â¶§¹®¿¡½Ã·áÀǾ纯ȭ¿¡  ¹Î°¨ÇÏ°Ô¹ÝÀÀÇÑ´Ù.)  cathodecathodeanode  protection  electrodeelectrode  samplesample  koh electrolyte  oh      oxygen analyzers  electrolytic oxygen   analyzers:  micro fuel cell  principle of operation  measures % to ppmlevels  (% ~ ppm±îÁöÃøÁ¤°¡´É)  low cost disposable sensor with   
limited lifetime.
(Àú°¡, Á¦Çѵȼö¸í¶§¹®¿¡Æ¯Á¤½Ã°£  µ¿¾È»ç¿ëÈÄÆó±âÇÑ´Ù.)       membrane  cathode  anode  electrolyte  sample    oxygen analyzers  electrolytic oxygen   analyzers:  micro fuel cell  principle of operation  some versions flow sensitive  (¸ÞÀÌÄ¿¿¡µû¶ó, ½Ã·áÀǾ纯ȭ¿¡  ¹Î°¨ÇÏ°Ô¹ÝÀÀÇϴ°æ¿ìµµÀÖ´Ù.)  membranes can be contaminated   and make the oxygen shock effect   
worse.
(menbraneÀÌ¿À¿°µÇ¸é oxygen   shock effect¸¦´õ¾ÇÈ­½Ãų¼öÀÖ´Ù.)       membrane  cathode  anode  electrolyte  sample    oxygen analyzers  electrolytic oxygen   analyzers:  micro fuel cell  principle of operation  contamination can also poison the   cathode and cause the electrolyte to   degenerate  (¿À¿°¹°ÁúÀºÀü±Ø¿¡¾Ç¿µÇâÀ»Á־ÀüÇØÁúÀǺ¯ÁúÀ»°¡Á®¿Ã¼öÀÖ´Ù.)       membrane  cathode  anode  electrolyte  sample    oxygen analyzers  electrolytic oxygen analyzers  advantages (micro fuel cell)  (ÀåÁ¡)  low cost  (Àú°¡)  
sensor is a ¡°commodity¡±to be replaced as needed
(¼¾¼­´ÂÇÊ¿ä½Ã¸¶´Ù½±°Ô±¸ÇÏ¿©½±°Ô±³Ã¼°¡°¡´ÉÇÏ´Ù.)
  oxygen analyzers  electrolytic oxygen analyzers  disadvantages (micro fuel cell)  (´ÜÁ¡)  sensors have to be replaced regularly  (¼¾¼­´ÂÁ¤±âÀûÀ¸·Î±³Ã¼ÇؾßÇÑ´Ù.)  
transmitters / analyzers have to be calibrated regularly   (ÀÌÇÏ »ý·«)

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