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0°ÇÀÇ Èı⺸±â»ê¼ÒºÐ¼®±â ÀÛµ¿¿ø¸®(electrolyte)¿¡ ´ëÇØ ¼³¸íÇÑ Âü°íÀÚ·áÀÔ´Ï´Ù.
1Àå Electrolytic Oxygen Analyzers
2Àå HerschCell
3Àå Micro Fuel Cell
1. Advantages (Micro Fuel Cell)
2. Disadvantages (Micro Fuel Cell)
¢ß±Â¸ð´×°èÃø±â oxygen analyzer: electrolytic oxygen analyzers oxygen analyzer: electrolytic oxygen analyzers oxygen analyzers electrolytic oxygen analyzers principle of operation
two types of electrolytic or galvanic sensors :
-hersch
-micro fuel cell
oxygen analyzers electrolytic oxygen analyzers principle of operation in the presence of oxygen, galvanic cells (or battery cells) develop an electromagnetic field as the result of a chemical
reaction.
(°¥¹Ù´Ð¼¿Àº, »ê¼Ò¿ÍÀÇ ÈÇйÝÀÀÀÇ°á°ú·Î¼ÀüÀÚ±âÀåÀ» ¹ß»ý½ÃŲ´Ù.) current is measured and calibrated to the oxygen concentration (¿©±â¼¹ß»ýÇÑÀü·ù¸¦ ÃøÁ¤ÇÏ°í, »ê¼ÒÀÇÇÔ·®¿¡´ëÇØ ±³Á¤ÇÑ´Ù.) oxygen analyzers electrolytic oxygen analyzers principle of operation
a depleting sensor has a measurement reaction
that consumes the anode (¼Ò¸ð¼º¼¾¼ÀÇ°æ¿ì, Àü±ØÀ»¼Ò¸ð½ÃÅ°´Â ¹ÝÀÀÀ¸·ÎÀü·ù¸¦¹ß»ý½ÃŲ´Ù.) the electrode lifetime is limited (Àü±ØÀǼö¸íÀÌÁ¦ÇÑÀûÀÌ´Ù.) oxygen analyzers electrolytic oxygen analyzers: herschcell principle of operation sensitive, uhp versions have ldl down to 1 ppb (ÃøÁ¤À̹ΰ¨ÇÏ°í, ÃÊ°í¼øµµ¿ëÀºÃÖÀú 1ppb ±îÁöÃøÁ¤ÀÌ°¡´É) sample is in direct contact with the electrolyte & contaminants can quickly degrade the electrolyte and possibly poison the silver cathode (½Ã·á´ÂÀüÇؾװúÁ÷Á¢Á¢ÃË& ¿À¿°¹°ÁúÀºÀüÇؾ×ÀÇÇ°¼ºÀ»±Þ°ÝÈ÷ ¶³¾î¶ß¸®°ÔµÇ¾îÀü±Ø¿¡¾Ç¿µÇâÀ» ¹ÌÄ£´Ù.) cathodecathodeanode protection electrodeelectrode samplesample koh electrolyte oh oxygen analyzers electrolytic oxygen analyzers: herschcell principle of operation bubbling sample gas causes rapid evaporation and requires frequent water addition, which can cause spiking.bubbling causes noise, and the sensor is very sensitive to sample flow changes (°ÅÇ°À»ÀÏÀ¸Å°´Â½Ã·á°¡½º´Â¼öºÐÀÇ Áõ¹ßÀ»¾ß±â½ÃŲ´Ù.°ÅÇ°Àºnoise¸¦ ¹ß»ý½ÃÅ°±â¶§¹®¿¡½Ã·áÀǾ纯ȿ¡ ¹Î°¨ÇÏ°Ô¹ÝÀÀÇÑ´Ù.) cathodecathodeanode protection electrodeelectrode samplesample koh electrolyte oh oxygen analyzers electrolytic oxygen analyzers: micro fuel cell principle of operation measures % to ppmlevels (% ~ ppm±îÁöÃøÁ¤°¡´É) low cost disposable sensor with
limited lifetime.
(Àú°¡, Á¦Çѵȼö¸í¶§¹®¿¡Æ¯Á¤½Ã°£ µ¿¾È»ç¿ëÈÄÆó±âÇÑ´Ù.) membrane cathode anode electrolyte sample oxygen analyzers electrolytic oxygen analyzers: micro fuel cell principle of operation some versions flow sensitive (¸ÞÀÌÄ¿¿¡µû¶ó, ½Ã·áÀǾ纯ȿ¡ ¹Î°¨ÇÏ°Ô¹ÝÀÀÇϴ°æ¿ìµµÀÖ´Ù.) membranes can be contaminated and make the oxygen shock effect
worse.
(menbraneÀÌ¿À¿°µÇ¸é oxygen shock effect¸¦´õ¾ÇȽÃų¼öÀÖ´Ù.) membrane cathode anode electrolyte sample oxygen analyzers electrolytic oxygen analyzers: micro fuel cell principle of operation contamination can also poison the cathode and cause the electrolyte to degenerate (¿À¿°¹°ÁúÀºÀü±Ø¿¡¾Ç¿µÇâÀ»ÁÖ¾î ÀüÇØÁúÀǺ¯ÁúÀ»°¡Á®¿Ã¼öÀÖ´Ù.) membrane cathode anode electrolyte sample oxygen analyzers electrolytic oxygen analyzers advantages (micro fuel cell) (ÀåÁ¡) low cost (Àú°¡)
sensor is a ¡°commodity¡±to be replaced as needed
(¼¾¼´ÂÇÊ¿ä½Ã¸¶´Ù½±°Ô±¸ÇÏ¿©½±°Ô±³Ã¼°¡°¡´ÉÇÏ´Ù.)
oxygen analyzers electrolytic oxygen analyzers disadvantages (micro fuel cell) (´ÜÁ¡) sensors have to be replaced regularly (¼¾¼´ÂÁ¤±âÀûÀ¸·Î±³Ã¼ÇؾßÇÑ´Ù.)
transmitters / analyzers have to be calibrated regularly (ÀÌÇÏ »ý·«)
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Æ÷ÀÎÆ® : ÀÚ·á 1°Ç´ç ÃÖ´ë 5,000P Áö±Þ
Çö±Ý : ÀÚ·á 1°Ç´ç ÃÖ´ë 2,000¿ø Áö±Þ