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thermodynamic relations ÀÚ·áÀÔ´Ï´Ù
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thermodynamic relations¿¡ °üÇÑ ÀÚ·áÀÔ´Ï´Ù.
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1. Equation of state (section 3.4, 11.1)
2. Useful Mathematical relations (section 11.2)
3. Maxwell relations (section 11.3)
4. Internal energy, enthalpy, entropyÀÇ ÀÏ¹Ý½Ä (section 11.4)
5. Other relations(section 11.5)
6. Construction of tables of thermodynamics properties(section 11.6)
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summary
ch.11 thermodynamic relations
1.equation of state (section
3.4, 11.1)
1) ÀÌ»ó±âü
o from observation () > ,
2) ½ÇÁ¦±âü
o ¾ÐÃ༺ÀÎÀÚ (section 3.4 ÂüÁ¶, fig.
3.11)
½ÇÁ¦ ±âü´Â ÀÌ»ó ±âü·ÎºÎÅÍ ÀÌÅ», ±× Á¤µµ Ç¥½Ã-&
gt; ¾ÐÃ༺ ÀÎÀÚ
,
ÀϹÝÈµÈ ¾ÐÃ༺ÀÎÀÚ-section 3.4 ÂüÁ¶, ap
pendix fig.a-1 ~a.3)
o virial »óŽÄ-½ÄÀÇ ±¸¼º
from observation of the behav
ior of real gases (fig.3.10)
-> ,
o van der waals »óŽÄ
> ½ÄÀÇ ±¸¼º
> °è¼öÀÇ ÀǹÌ, °è¼ö ±¸ÇÏ´Â ¹æ¹ý ¼÷Áö
> variation : redlich-kwon
g »óŽÄ
o ±âŸ multi-constant »óŽÄ
beatti-bridgemann »óŽÄ
bwr »óŽÄ
example xxxx.xx.xx.useful mat
hematical relations (section 11.2)
1) ¿ÏÀü ¹ÌºÐ
o (ÀÌÇÏ »ý·«)
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